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he practises as a naturopath here in the uk
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Doctor who couldn't qualify from medical school. No offence but there's absolutely no regulation of naturopathy in the UK which means your brother-in-law could be as qualified as in medical treatment as the kid flipping burgers in McDonalds.
There is absolutely no scientific evidence that you can alter the pH of your body through diet or that the pH of your body even has any meaningful effect, even if you could change it. Saliva samples (from which I'm assuming you are evaluating your oral pH levels) will fluctuate depending on what you've recently eaten or drunk from the residue left in your mouth but this won't have any effect on the rest of your body.
If it was physically possible to alter your pH level and beat cancer I guarantee that it wouldn't be the sole preserve of naturopaths and pharmaceutical companies would be falling over themselves to make expensive pills that would change your body's pH level.